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Asymmetric Allyltributylstannane Addition to Ketones Catalyzed by Chiral Indium(III)-PYBOX Complex

✍ Scribed by Jun Lu; Shun-Jun Ji

Publisher: John Wiley and Sons
Year: 2006
Tongue: English
Weight: 51 KB
Volume: 24
Category: Article
ISSN: 0256-7660
DOI: 10.1002/cjoc.200690270

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✦ Synopsis

Abstract

An indium complex of chiral pyridine bis(oxazoline) (PYBOX) has been applied to the catalytic asymmetric allylation of ketones. It has been found that this chiral indium complex is strong enough to promote the reaction of ketones with allyltributylstannane smoothly. The products were obtained in moderate yields with low to moderate enantioselectivities.

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## Abstract For Abstract see ChemInform Abstract in Full Text.