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Asymmetric Allylic Oxidation Catalyzed by Copper(I) Complexes of Chiral (Iminophosphoranyl)ferrocenes

โœ Scribed by Hoang, Vo D. M.; Reddy, Pattubala A. N.; Kim, Tae-Jeong


Book ID
118021521
Publisher
American Chemical Society
Year
2008
Tongue
English
Weight
60 KB
Volume
27
Category
Article
ISSN
0276-7333

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Allylic oxidation catalyzed by chiral di
โœ Christoph J. Fahrni ๐Ÿ“‚ Article ๐Ÿ“… 1998 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 375 KB

Copper(l) complexes prepared in situ from Cu(I)(CH3CN)4PF 6 and several chiral dinucleating ligands have been studied as catalysts for the allylic oxidation of cyclohexene with tert-butyl perbenzoate. Cyclohexenyl benzoate was obtained in yields ranging from 30-92% and with enantioselectivities up t