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Allylic oxidation catalyzed by chiral dinuclear copper complexes

✍ Scribed by Christoph J. Fahrni

Publisher: Elsevier Science
Year: 1998
Tongue: French
Weight: 375 KB
Volume: 54
Category: Article
ISSN: 0040-4020
DOI: 10.1016/s0040-4020(98)00244-0

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✦ Synopsis

Copper(l) complexes prepared in situ from Cu(I)(CH3CN)4PF 6 and several chiral dinucleating ligands have been studied as catalysts for the allylic oxidation of cyclohexene with tert-butyl perbenzoate. Cyclohexenyl benzoate was obtained in yields ranging from 30-92% and with enantioselectivities up to 37% ee. Surprisingly, the formation of an imide has also been observed in significant yields.

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