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Asymmetric Allylic Alkylation of Cyclic Vinylogous Esters and Thioesters by Pd-Catalyzed Decarboxylation of Enol Carbonate and β-Ketoester Substrates.

✍ Scribed by Barry M. Trost; Robert N. Bream; Jiayi Xu

Publisher
John Wiley and Sons
Year
2006
Weight
41 KB
Volume
37
Category
Article
ISSN
0931-7597

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Abstract

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📜 SIMILAR VOLUMES

Asymmetric Allylic Alkylation of Cyclic
Asymmetric Allylic Alkylation of Cyclic Vinylogous Esters and Thioesters by Pd-Catalyzed Decarboxylation of Enol Carbonate and β-Ketoester Substrates
✍ Barry M. Trost; Robert N. Bream; Jiayi Xu 📂 Article 📅 2006 🏛 John Wiley and Sons 🌐 English ⚖ 159 KB 👁 3 views

b-Alkoxy a,b-unsaturated ketones are versatile synthons for organic synthesis, as they serve as masked 1,3-dicarbonyl compounds in which the two ketone groups and adjacent carbon atoms may be selectively functionalized. Polysubstituted cyclic vinylogous esters are particularly useful for the synthes