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Asymmetric Allylic Alkylation of Cyclic Vinylogous Esters and Thioesters by Pd-Catalyzed Decarboxylation of Enol Carbonate and β-Ketoester Substrates

✍ Scribed by Barry M. Trost; Robert N. Bream; Jiayi Xu

Publisher: John Wiley and Sons
Year: 2006
Tongue: English
Weight: 159 KB
Volume: 118
Category: Article
ISSN: 0044-8249
DOI: 10.1002/ange.200504421

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Asymmetric Allylic Alkylation of Cyclic

Asymmetric Allylic Alkylation of Cyclic Vinylogous Esters and Thioesters by Pd-Catalyzed Decarboxylation of Enol Carbonate and β-Ketoester Substrates

✍ Barry M. Trost; Robert N. Bream; Jiayi Xu 📂 Article 📅 2006 🏛 John Wiley and Sons 🌐 English ⚖ 159 KB 👁 3 views

b-Alkoxy a,b-unsaturated ketones are versatile synthons for organic synthesis, as they serve as masked 1,3-dicarbonyl compounds in which the two ketone groups and adjacent carbon atoms may be selectively functionalized. Polysubstituted cyclic vinylogous esters are particularly useful for the synthes

Asymmetric Allylic Alkylation of Cyclic

Asymmetric Allylic Alkylation of Cyclic Vinylogous Esters and Thioesters by Pd-Catalyzed Decarboxylation of Enol Carbonate and β-Ketoester Substrates.

✍ Barry M. Trost; Robert N. Bream; Jiayi Xu 📂 Article 📅 2006 🏛 John Wiley and Sons ⚖ 41 KB

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