✦ LIBER ✦

Asymmetric allylation reactions of aromatic aldehydes with allyltrichlorosilane catalyzed by chiral bisformamide-type organocatalysts

✍ Scribed by Yuya Tanimura; Kaori Ishimaru

Book ID: 113929656
Publisher: Elsevier Science
Year: 2012
Tongue: English
Weight: 526 KB
Volume: 23
Category: Article
ISSN: 0957-4166
DOI: 10.1016/j.tetasy.2012.02.015

No coin nor oath required. For personal study only.

📜 SIMILAR VOLUMES

Asymmetric allylation of aldehydes with

Asymmetric allylation of aldehydes with allyltrichlorosilane promoted by chiral sulfoxides

✍ Antonio Massa; Andrei V. Malkov; Pavel Kočovský; Arrigo Scettri 📂 Article 📅 2003 🏛 Elsevier Science 🌐 French ⚖ 68 KB

Allylation of aldehydes with allyltrichlorosilane in the presence of sulfoxides is reported. The use of excess of (R)-methyl-p-tolylsulfoxide resulted in the formation of the corresponding homoallylic alcohols in good yields and moderate enantiomeric excesses.

Asymmetric Allylation of Aldehydes with

Asymmetric Allylation of Aldehydes with Allyltrichlorosilane Promoted by Chiral Sulfoxides.

✍ Antonio Massa; Andrei V. Malkov; Pavel Kocovsky; Arrigo Scettri 📂 Article 📅 2003 🏛 John Wiley and Sons ⚖ 83 KB 👁 2 views

Chiral 2,2‘-Bipyridine-Type N-Monoxides

Chiral 2,2‘-Bipyridine-Type N-Monoxides as Organocatalysts in the Enantioselective Allylation of Aldehydes with Allyltrichlorosilane†

✍ Malkov, Andrei V.; Orsini, Monica; Pernazza, Daniele; Muir, Ken W.; Langer, Vrat 📂 Article 📅 2002 🏛 American Chemical Society 🌐 English ⚖ 55 KB

ChemInform Abstract: Chiral 2,2′-Bipyrid

ChemInform Abstract: Chiral 2,2′-Bipyridine-Type N-Monoxides as Organocatalysts in the Enantioselective Allylation of Aldehydes with Allyltrichlorosilane.

✍ Andrei V. Malkov; Monica Orsini; Daniele Pernazza; Ken W. Muir; Vratislav Langer 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 33 KB 👁 1 views

On the Mechanism of Asymmetric Allylatio

On the Mechanism of Asymmetric Allylation of Aldehydes with Allyltrichlorosilanes Catalyzed by QUINOX, a Chiral Isoquinoline N -Oxide

✍ Malkov, Andrei V.; Ramírez-López, Pedro; Biedermannová (née Bendová), Lada; Rulí 📂 Article 📅 2008 🏛 American Chemical Society 🌐 English ⚖ 830 KB

Asymmetric allylation of aromatic aldehy

Asymmetric allylation of aromatic aldehydes catalyzed by chiral phosphoramides prepared from (S)-proline

✍ Katsuhiko Iseki; Yoshichika Kuroki; Mie Takahashi; Satoshi Kishimoto; Yoshiro Ko 📂 Article 📅 1997 🏛 Elsevier Science 🌐 French ⚖ 870 KB

Chiral phosphoramides prepared from (S)-proline were used to catalyze the allylation and crotylation of aromatic aldehydes with allylic trichlorosilanes in good enantioseleetive yields. Phosphoramides 4d and 4m gave chiral homoallylic alcohols and their enantiomers, respectively, with similar levels