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Asymmetric Allylation of Aldehydes with Chiral Lewis Bases

โœ Scribed by Denmark, Scott E.; Coe, Diane M.; Pratt, Norman E.; Griedel, Brian D.


Book ID
118069564
Publisher
American Chemical Society
Year
1994
Tongue
English
Weight
359 KB
Volume
59
Category
Article
ISSN
0022-3263

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Asymmetric allylation of aldehydes with
โœ Antonio Massa; Andrei V. Malkov; Pavel Koฤovskรฝ; Arrigo Scettri ๐Ÿ“‚ Article ๐Ÿ“… 2003 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 68 KB

Allylation of aldehydes with allyltrichlorosilane in the presence of sulfoxides is reported. The use of excess of (R)-methyl-p-tolylsulfoxide resulted in the formation of the corresponding homoallylic alcohols in good yields and moderate enantiomeric excesses.