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Asymmetric alkylation reactions of camphor-based imide enolate

✍ Scribed by Tu-Hsin Yan; Vir-Vir Chu; Ta-Chin Lin; Chih-Hung Wu; Ling-Hsiang Liu

Book ID
108382214
Publisher
Elsevier Science
Year
1991
Tongue
French
Weight
172 KB
Volume
32
Category
Article
ISSN
0040-4039

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Efficient asymmetric hydrogenations of c
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The trisubstituted olefinic bond of sultam-imides 2 was hydrogenated in the presence of Pd/C with >90% diastereoface discrimination to give after saponification recovered auxiliary z and the B-substituted carboxylic acids 5 or 6 in high e.e..