Asymmetric aldol reactions of trifluoromethyl ketones with a chiral Ni(II) complex of glycine: Stereocontrolling effect of the trifluoromethyl group
β Scribed by Vadim A Soloshonok; Dimitry V Avilov; Valery P Kukhar
- Publisher
- Elsevier Science
- Year
- 1996
- Tongue
- French
- Weight
- 694 KB
- Volume
- 52
- Category
- Article
- ISSN
- 0040-4020
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π SIMILAR VOLUMES
Stereoselectivity of aldol reactions between aliphatic aldehydes and Ni(ll)-complex of chiral non-racemic Schiff base of glycine with (S)-o-[N-(N-benzylprolyl)amino]benzophenone (BPB) in the presence of excess of MeONa, has been studied as a function of time, reaction conditions and nature of an ald
The LiC1/base-assisted asymmetric aldol-type addition reaction between the N-(p-methoxyphenyl)imine of trifluoroacetaldehyde and the chiral non-racemic Ni(II) complex of the Schiff base of glycine with (S)-o-[N-(Nbenzylprolyl)amino]benzophenone was lound to proceed with excellent chemical and stereo
## 1997 aminocarboxylic acids aminocarboxylic acids (hydrazinocarboxylic acids) and esters (acyclic compounds) P 0270 ## 40 -103 Highly Diastereoselective Aza-Aldol Reactions of a Chiral Ni(II) Complex of Glycine with Imines. An Efficient Asymmetric Approach to 3-Perfluoroalkyl-2,3-diamino Acids.
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