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Asymmetric [2,3]-Rearrangement of Glycine-Derived Allyl Ammonium Ylids

✍ Scribed by Workman, James A.; Garrido, Neil P.; Sançon, Julien; Roberts, Edward; Wessel, Hans Peter; Sweeney, J. B.


Book ID
120442459
Publisher
American Chemical Society
Year
2005
Tongue
English
Weight
51 KB
Volume
127
Category
Article
ISSN
0002-7863

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An investigation of the Lewis acid mediated [2,3]-sigmatropic rearrangement of allylic ammonium ylides has been conducted by employing various bases and boron Lewis acids. Using BBr 3 together with the phosphazene base 6, various allylic amines could be rearranged in good yields with low to excellen