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Asymmetric [2,3]-Rearrangement of Glycine-Derived Allyl Ammonium Ylids.

✍ Scribed by James A. Workman; Neil P. Garrido; Julien Sancon; Edward Roberts; Hans Peter Wessel; J. B. Sweeney


Book ID
101979168
Publisher
John Wiley and Sons
Year
2005
Weight
37 KB
Volume
36
Category
Article
ISSN
0931-7597

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Lewis acid mediated [2,3]-sigmatropic re
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An investigation of the Lewis acid mediated [2,3]-sigmatropic rearrangement of allylic ammonium ylides has been conducted by employing various bases and boron Lewis acids. Using BBr 3 together with the phosphazene base 6, various allylic amines could be rearranged in good yields with low to excellen