As≡UF 3 Molecule with a Weak Triple Bond to Uranium
✍ Scribed by Andrews, Lester; Wang, Xuefeng; Roos, Björn O.
- Book ID
- 118039447
- Publisher
- American Chemical Society
- Year
- 2009
- Tongue
- English
- Weight
- 714 KB
- Volume
- 48
- Category
- Article
- ISSN
- 0020-1669
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## Abstract Seite an Seite: Die Zugabe von Zink zu einem Gemisch von [{Cp\*RuCl}~4~] und Pentamethyl‐2,3‐dihydro‐1,3‐diborol (C~3~B~2~Me~5~H) in THF führt zu drei bekannten Doppel‐ und Tripeldeckerkomplexen von [C~3~B~2~Me~5~]^−^, darüber hinaus aber auch zu einem verschobenen Tripeldeckerkomplex (
## Abstract Colliding double deckers: Addition of zinc to a reaction mixture of [{Cp\*RuCl}~4~]/pentamethyl‐2,3‐dihydro‐1,3‐diborole (C~3~B~2~Me~5~H) in THF leads to three known double‐ and triple‐decker complexes of [C~3~B~2~Me~5~]^−^, and unexpectedly to the slipped triple‐decker (see picture) wi