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Fusion of a 1,3-Diboraruthenocene to Form a Slipped μ-Hexahydrotetraboranaphthalene Triple-Decker Complex with Two Axial CH Bonds

✍ Scribed by Elena V. Mutseneck; Hubert Wadepohl; Markus Enders; Alexander R. Kudinov; Walter Siebert

Publisher
John Wiley and Sons
Year
2009
Tongue
English
Weight
283 KB
Volume
48
Category
Article
ISSN
0044-8249

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✦ Synopsis

Abstract

Colliding double deckers: Addition of zinc to a reaction mixture of [{Cp*RuCl}~4~]/pentamethyl‐2,3‐dihydro‐1,3‐diborole (C~3~B~2~Me~5~H) in THF leads to three known double‐ and triple‐decker complexes of [C~3~B~2~Me~5~]^−^, and unexpectedly to the slipped triple‐decker (see picture) with two fused diborole rings. The endo CH bonds of two MeCH groups donate two additional electrons to achieve the stable 34 VE configuration.magnified image

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Fusion of a 1,3-Diboraruthenocene to For
Fusion of a 1,3-Diboraruthenocene to Form a Slipped μ-Hexahydrotetraboranaphthalene Triple-Decker Complex with Two Axial CH Bonds
✍ Elena V. Mutseneck; Hubert Wadepohl; Markus Enders; Alexander R. Kudinov; Walter 📂 Article 📅 2009 🏛 John Wiley and Sons 🌐 English ⚖ 283 KB

## Abstract Seite an Seite: Die Zugabe von Zink zu einem Gemisch von [{Cp\*RuCl}~4~] und Pentamethyl‐2,3‐dihydro‐1,3‐diborol (C~3~B~2~Me~5~H) in THF führt zu drei bekannten Doppel‐ und Tripeldeckerkomplexen von [C~3~B~2~Me~5~]^−^, darüber hinaus aber auch zu einem verschobenen Tripeldeckerkomplex (