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Assignment of the 1H, 13C and 15N NMR spectra of methyl β-D-glucopyranoside tetranitrate, β-cellobiose octanitrate and cellulose trinitrate by two-dimensional homonuclear and heteronuclear 13C1H and 15NOC1H shift correlation spectroscopy

✍ Scribed by T. Axenrod; B. Liang; S. Bulusu

Publisher
John Wiley and Sons
Year
1989
Tongue
English
Weight
597 KB
Volume
27
Category
Article
ISSN
0749-1581

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✦ Synopsis

The unambiguous assignment of all the 'H, I3C and "N resonance signals in methyl /h-glucopyranoside tetranitrate and /hellobiow octanitrate was made using homonuclear and heteronuclear * 3C- 1H and"N-O-C-'H two-dimensional shift correlation NMR experiments. Solvent-induced shifts were used to confirm the "C-'H correlations in fl-cellobiose octanitrate. Based on these observations and selective decoupling experiments, the "N resonance signals in cellulose trinitrate were tentatively assigned. KEY WORDS Nitrocellulose Cellulose trinitrate Cellobiose octanitrate Methyl fi-D-ghcopyranoside tetranitrate I5N NMR

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