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Assignment of finely resolved 13C NMR spectra of poly(methyl methacrylate), 2. Methylene carbon

โœ Scribed by Tokiji Kawamura; Naoki Toshima; Kei Matsuzaki


Publisher
John Wiley and Sons
Year
1994
Tongue
English
Weight
176 KB
Volume
195
Category
Article
ISSN
1022-1352

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โœฆ Synopsis


Abstract

The ^13^C methylene carbon absorptions of poly(methyl methacrylate) with a random structure were assigned in terms of tetrad sequences using the 2D COSY (^1^Hโ€^13^C) NMR spectrum and by comparison with the absorptions of isotacticโ€rich and syndiotacticโ€rich poly(methyl methacrylate)s. The rrr, rmr and mmr tetrads were further assigned in terms of hexad sequences.


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