Assignment of finely resolved 13C NMR spectra of poly(methyl methacrylate), 2. Methylene carbon
โ Scribed by Tokiji Kawamura; Naoki Toshima; Kei Matsuzaki
- Publisher
- John Wiley and Sons
- Year
- 1994
- Tongue
- English
- Weight
- 176 KB
- Volume
- 195
- Category
- Article
- ISSN
- 1022-1352
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โฆ Synopsis
Abstract
The ^13^C methylene carbon absorptions of poly(methyl methacrylate) with a random structure were assigned in terms of tetrad sequences using the 2D COSY (^1^Hโ^13^C) NMR spectrum and by comparison with the absorptions of isotacticโrich and syndiotacticโrich poly(methyl methacrylate)s. The rrr, rmr and mmr tetrads were further assigned in terms of hexad sequences.
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## Abstract ^13^C NMR spectra of poly(methyl acrylate) (PMA), poly(ethyl acrylate) (PEA), poly(isopropyl acrylate) (PIPA), poly(butyl acrylate) (PBA), and poly(isobutyl acrylate) (PIBA) with various tacticities were determined. It was found that methine carbon resonances of PIPA split into triad se
## Abstract Resonances in the ^1^H and ^13^C NMR spectra of freeโradical polymerised poly(1โnaphthylmethyl acrylate) (PNMA) and poly[2โ(1โnaphthyl)ethyl acrylate] (PNEA) have been assigned using twoโdimensional techniques. The stereosequence distribution in both polymers obeyed Bernoullian statisti