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Assignment of EPR transitions in a manganese-containing lipoxygenase and prediction of local structure

✍ Scribed by B. J. Gaffney; C. Su; E. H. Oliw

Book ID
105719548
Publisher
Springer Vienna
Year
2001
Tongue
English
Weight
688 KB
Volume
21
Category
Article
ISSN
0937-9347

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Structure of a five-membered ring containing a phosphinyl radical: ab initio predictions and single-crystal EPR study
✍ Michel Geoffroy; Gustavo Terron; Gerald Bernardinelli πŸ“‚ Article πŸ“… 1991 πŸ› Elsevier Science 🌐 English βš– 480 KB

The geometry of the tive-membered ring (1) containing a phosphinyl radical is studied by ab initio molecular orbital calculations. X-irradiation of a single crystal of 1,3benzazaphosphole (2) generates the cyclic phosphinyl radical (3) whose EPR parameters are obtained and compared with those calcul