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Assignment of 13C NMR data of methyl (+)-hardwickiate and its derivatives

✍ Scribed by Marta Costa; Fred Y. Fujiwara; Paulo M. Imamura

Publisher: John Wiley and Sons
Year: 1998
Tongue: English
Weight: 173 KB
Volume: 36
Category: Article
ISSN: 0749-1581
DOI: 10.1002/(sici)1097-458x(199807)36:7<542::aid-omr334>3.0.co;2-7

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✦ Synopsis

Despite the large number of clerodanes isolated as natural products in the last decade, the correct 13C NMR chemical shift assignments of some carbons are still in doubt. In order to provide unambiguous assignments of the chemical shifts of clerodane diterpenes, a complete 13C NMR spectral analysis of methyl (])-hardwickiate and 14 hemisynthetic derivatives is reported.

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