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Assessing the Rates of Ring-Opening of Aziridinium and Azetidinium Ions: A Dramatic Ring Size Effect

✍ Scribed by De Rycke, Nicolas; David, Olivier; Couty, François

Book ID
127014661
Publisher
American Chemical Society
Year
2011
Tongue
English
Weight
728 KB
Volume
13
Category
Article
ISSN
1523-7060

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Metal Complexes with Macrocyclic Ligands
Metal Complexes with Macrocyclic Ligands. XI. Ring size effect on the complexation rates with transition metal ions
✍ Alex P. Leugger; Liselotte Hertli; Thomas A. Kaden 📂 Article 📅 1978 🏛 John Wiley and Sons 🌐 German ⚖ 509 KB

## Abstract The 12‐16 membered tetraazamacrocycles **1**‐**6** were synthesized, their protonation constants and complexation kinetics measured at 25° and I = 0.50. The results of __Table 1__ Show that p__K__ is strongly influenced by the ring size whereas p__K__ and p__K__ are relatively insensiti