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Broensted Acid Mediated Ring-Opening Reactions of Methylenecyclopropanes: A Dramatic Counter Ion Effect.

✍ Scribed by Li-Xiong Shao; Jin-Wen Huang; Min Shi


Publisher
John Wiley and Sons
Year
2005
Weight
27 KB
Volume
36
Category
Article
ISSN
0931-7597

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Understanding the Ring-Opening Reaction
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## Abstract The primary‐amine‐initiated polymerization of __α__‐amino acid __N__‐carboxyanhydride (NCA) is a widely‐used and promising way to synthesize polypeptide‐involved materials with various applications. The nucleophilic attack mechanism, also known as normal amine mechanism of ring opening