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Ascorbate-induced oxidation of formate by peroxodisulfate: product yields, kinetics and mechanism

✍ Scribed by Maria A. Curtin; Irwin A. Taub; Kenneth Kustin; Narith Sao; Jeremy R. Duvall; Katharine I. Davies; Christopher J. Doona; Edward W. Ross


Book ID
111759713
Publisher
Springer Netherlands
Year
2004
Tongue
English
Weight
209 KB
Volume
30
Category
Article
ISSN
0922-6168

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✍ Lakshmanan Venkatasubramanian; Periasamy Dharmalingam; Pichai Maruthamuthu πŸ“‚ Article πŸ“… 1990 πŸ› John Wiley and Sons 🌐 English βš– 501 KB

## Abstract Excitation of Ru(bipy)~3~^2+^ ion by visible radiation of wavelength Ξ» = 436 nm in aqueous medium in presence of inorganic peroxides, peroxomonosulfate (PMS), peroxodisulfate (PDS), and peroxodiphosphate (PDP) was found to generate Ru(bipy)~3~^3+^. The kinetics of this photochemical oxi