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[As3Br12]3– and [As8I28]4– – Structurally Novel, Discrete Halogenoarsenate(III) Ions

✍ Scribed by Prof. Dr. William S. Sheldrick; Dipl.-Chem. Hans-Joachim Häusler


Book ID
101558635
Publisher
John Wiley and Sons
Year
1987
Tongue
English
Weight
343 KB
Volume
26
Category
Article
ISSN
0044-8249

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The reactions of water-soluble phosphanes P(CH,OH), (1) and Ph2PCH20H (2) with NaAuC14 in aqueous or alcoholic media, produced the water/alcoholic-soluble Au' complexes [Au(P(CH,OH),),]+ (3) and [Au(Ph2PCH20H):J+ (4) in near quantitative yields. The X-ray structures of 3 and 4, reported in this pape