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Arylation with Unsymmetrical Diaryliodonium Salts: A Chemoselectivity Study

✍ Scribed by Malmgren, Joel; Santoro, Stefano; Jalalian, Nazli; Himo, Fahmi; Olofsson, Berit

Book ID: 121723095
Publisher: John Wiley and Sons
Year: 2013
Tongue: English
Weight: 613 KB
Volume: 19
Category: Article
ISSN: 0947-6539
DOI: 10.1002/chem.201300860

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Highly Efficient Arylation of Malonates with Diaryliodonium Salts. -The sodium salt of β-dicarbonyl compounds such as the diethyl malonates (I) readily reacts with symmetrical diaryliodonium salts (II) to yield the arylated derivatives (III). Unsymmetrical substrates [cf. (IV)] react with transfer o