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Arylation of Aromatic Compounds by the Meerwein Reaction. Evidence for Aryl Radicals from Orientation Studies 1

โœ Scribed by DICKERMAN, S. CARLTON; WEISS, KARL

Book ID
120090146
Publisher
American Chemical Society
Year
1957
Tongue
English
Weight
507 KB
Volume
22
Category
Article
ISSN
0022-3263

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Aryl radicals are generated by oxidation of aryl hydrazine with PbO2 or via photolysis of aryl iodide. Abstraction of deuterium from dideuteroglycine derivatives is demonstrated as a model for the possible reaction of 1,4-aryl diradicals with amino acid residues in proteins.