✦ LIBER ✦
Abstraction of deuterium from dideuteroglycine by aryl radical: A model for 1, 4-benzene diradical reactions with proteins
✍ Scribed by Rebecca Braslau; Marc O. Anderson
- Book ID
- 104259352
- Publisher
- Elsevier Science
- Year
- 1998
- Tongue
- French
- Weight
- 187 KB
- Volume
- 39
- Category
- Article
- ISSN
- 0040-4039
No coin nor oath required. For personal study only.
✦ Synopsis
Aryl radicals are generated by oxidation of aryl hydrazine with PbO2 or via photolysis of aryl iodide. Abstraction of deuterium from dideuteroglycine derivatives is demonstrated as a model for the possible reaction of 1,4-aryl diradicals with amino acid residues in proteins.