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Aryl radicals by copper(II) oxidation of hydrazines: A new method for the oxidative and reductive arylation of alkenes

✍ Scribed by Teresa Varea; Maria E. González-Núñez; Javier Rodrigo-Chiner; Gregorio Asensio


Publisher
Elsevier Science
Year
1989
Tongue
French
Weight
218 KB
Volume
30
Category
Article
ISSN
0040-4039

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The Mg-Oppenauer Oxidation as a Mild Met
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## Abstract Magnesium alkoxides undergo a hydride‐transfer oxidation with benzaldehyde as the oxidant. This magnesium variant of the Oppenauer oxidation was used for the synthesis of polyfunctional biaryl ketones. LiCl was found to promote this reaction by enhancing the solubility of magnesium alko