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Aryl Mesylates in Metal Catalyzed Homocoupling and Cross-Coupling Reactions. 2. Suzuki-Type Nickel-Catalyzed Cross-Coupling of Aryl Arenesulfonates and Aryl Mesylates with Arylboronic Acids

✍ Scribed by Percec, Virgil; Bae, Jin-Young; Hill, Dale H.

Book ID: 118034551
Publisher: American Chemical Society
Year: 1995
Tongue: English
Weight: 803 KB
Volume: 60
Category: Article
ISSN: 0022-3263
DOI: 10.1021/jo00109a044

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## Abstract For Abstract see ChemInform Abstract in Full Text.

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The cross-coupling reaction of arylboronic acids (1.3 equivs) with aryl methanesulfonates was carded out in the presence of anickel(O) catalyst(3 tool%) and K3PO~,nH20 (3 equivs). The use of toluene as the solvent and the nickel(O)-dppf catalyst prepared from NiC~(dppf) plus dppf with BuLi were reco