Artificial Photosynthetic Reaction Centers: Mimicking Sequential Electron and Triplet-Energy Transfer
β Scribed by Rodrigo E. Palacios; Gerdenis Kodis; Stephanie L. Gould; Linda de la Garza; Alicia Brune; Devens Gust; Thomas A. Moore; Ana L. Moore
- Publisher
- John Wiley and Sons
- Year
- 2005
- Tongue
- English
- Weight
- 246 KB
- Volume
- 6
- Category
- Article
- ISSN
- 1439-4235
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Vibrational coherence recently observed by Vos et al. has been analyzed to determine the rate of vibrational relaxation involved in the primary electron transfer (ET) in reaction centers. A modified ET model is introduced to determine multi-mode effects and the temperature dependence of ET for a ser
Samples were prepared in [DJDMSO at concentrations of 30-40 mM. The resonance of [DJDMSO (6 = 2.49) was used as an internal standard. The one-dimensional spectra were collected with 32 K data points and with spectral widths of +3000 or k2000 Hz. The two-dimensional DQF COSY experiments were acquired