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Arsenicum-centered Molybdenum–Vanadium polyoxometalates bearing transition metal complexes: Hydrothermal syntheses, crystal structures and magnetic properties

✍ Scribed by Fengyan Li; Lin Xu; Yongge Wei; Xinlong Wang; Wenju Wang; Enbo Wang


Publisher
Elsevier Science
Year
2005
Tongue
English
Weight
236 KB
Volume
753
Category
Article
ISSN
0022-2860

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## Abstract Two transition‐metal phosphites, Na~2~[M(HPO~3~)~2~] (M = Fe, Co) with a new structure type have been synthesised under mild hydrothermal conditions and the solid‐state structures have been elucidated by single‐crystal X‐ray diffraction studies. The structures are of a new type with the