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Hydrothermal syntheses, crystal structures and properties of 0-D, 1-D and 2-D organic–inorganic hybrid borotungstates constructed from Keggin-type heteropolyanion [α-BW12O40]5− and transition-metal complexes

✍ Scribed by Junwei Zhao; Yiping Song; Pengtao Ma; Jingping Wang; Jingyang Niu


Publisher
Elsevier Science
Year
2009
Tongue
English
Weight
604 KB
Volume
182
Category
Article
ISSN
0022-4596

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A novel two-dimensional infinite network organic -inorganic hybrid neodymium(III)-centered compound of formula (dmaH is obtained by the conventional selfassembly reaction of neodymium oxide, N,N-dimethylformamide and borotungstic acid (a-H 5 BW 12 O 40 •30H 2 O) in the mixed solvent of acetonitrile