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“Aromatization metalation” reaction

✍ Scribed by V. A. Nikanorov; V. I. Rozenberg; Yu. G. Bundel'; O. A. Reutov

Book ID
112438943
Publisher
Springer
Year
1974
Tongue
English
Weight
74 KB
Volume
23
Category
Article
ISSN
1573-9171

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Direct dimetaZation of aromatic thioethers gives with good yieZd the dizithiated species 3, 4, 2, g, 5, 26. The first four species aZlowed the simultaneous introduction of an eZectrophiZe in the thiomethyl group and in the &ng,while the Zast two species undergo &substitution in the ring.