𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Aromatic SRN1 reactions stimulated by sunlight - phenylation of dimsyl anion

✍ Scribed by S. Rajan; K. Muralimohan

Book ID
104242652
Publisher
Elsevier Science
Year
1978
Tongue
French
Weight
203 KB
Volume
19
Category
Article
ISSN
0040-4039

No coin nor oath required. For personal study only.

✦ Synopsis

Bunnett and his coworkers1 have successfully carried out many nucleophilic substitution reactions on simple halobeneenes under stimulation eitner by ammoniated electrons or light (around 300-380 nm) . These reactions according to them proceed via SDNl mechanism2. very ret ently

πŸ“œ SIMILAR VOLUMES

Reactions of N-thioacetylmorpholine anio
Reactions of N-thioacetylmorpholine anion with iodoarenes and 1-iodoadamantane by the SRN1 mechanism
✍ Marcelo C MurguΓ­a; Roberto A Rossi πŸ“‚ Article πŸ“… 1997 πŸ› Elsevier Science 🌐 French βš– 204 KB

The ~afion of N-acetylthiomorpholinΒ’ 2 was studied in photostimdated reactions with iodobenzene la and l-iodonaphthalene lb in DMSO, giving good yields of the substitution products 3a and 3b by the SR~I mechanism. The reaction of la with 2 is also induced with FeBr2. l-Iodoadamantane 4 did not react