Aromatic radical anions in neat solvents. Crown complex ion-pair formation
โ Scribed by Nelson, Gregory V.; Von Zelewsky, Alexander
- Book ID
- 121457160
- Publisher
- American Chemical Society
- Year
- 1975
- Tongue
- English
- Weight
- 401 KB
- Volume
- 97
- Category
- Article
- ISSN
- 0002-7863
No coin nor oath required. For personal study only.
๐ SIMILAR VOLUMES
## Abstract Contact ion pairs of aromatic radical anions, with a crown ether complex of potassium as cation in a neat aromatic hydrocarbon, can be obtained by reducing the aromatic hydrocarbon in which a small amount of crown ether is dissolved. The unpaired electron stays attached to one aromatic
The structure of ions and ion pairs of Meisenheimer and Janovsky o-complexes of 1,3,5trinitrobenzene has been studied by derivative spectroscopy and semiempitical quantum chemical PM3 and CNDO/S methods. On the base of comparison of theoretical and experimental electronic absorption spectra the thre