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Aromatic nucleophilic substitution. 21. Electronic structures of 1,3-dinitro-4-phenanthryl methyl ether and the 4,4-disubstituted 1,3-dinitrophenanthrene Meisenheimer complex

โœ Scribed by Sekiguchi, Shizen; Hirai, Motohiko; Ota, Etsuro; Hiratsuka, Hiroshi; Mori, Yuji; Tanaka, Shigeyuki


Book ID
126975342
Publisher
American Chemical Society
Year
1985
Tongue
English
Weight
494 KB
Volume
50
Category
Article
ISSN
0022-3263

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Aromatic nucleophilic substitution VIII.
โœ S. Sekiguchi; T. Takei; T. Aizawa; K. Okada ๐Ÿ“‚ Article ๐Ÿ“… 1977 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 200 KB

Ever since Servis' first observed by NMR spectrometry that in DMSO much faster formation of 1,3\_disubstituted anionic o complex (hereinafter referred to as 1,3-adduct) from 2,4,6\_trinitroanisole (TNA) and 'OCH3 is followed by a much slower attack on the l-position, considerable attention has been