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Aromatic nucleophilic substitution IV. Existence of 1,3- and 1,1-disubstituted meisenheimer complexes in the reactions of 1-sec-amino-2,4-dinitro-naphthalanes with sodium ethoxide

✍ Scribed by S. Sekiguchi; K. Shinozaki; T. Hirose; K. Matsui; T. Itagaki


Publisher
Elsevier Science
Year
1974
Tongue
French
Weight
190 KB
Volume
15
Category
Article
ISSN
0040-4039

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Aromatic nucleophilic substitution VIII.
✍ S. Sekiguchi; T. Takei; T. Aizawa; K. Okada πŸ“‚ Article πŸ“… 1977 πŸ› Elsevier Science 🌐 French βš– 200 KB

Ever since Servis' first observed by NMR spectrometry that in DMSO much faster formation of 1,3\_disubstituted anionic o complex (hereinafter referred to as 1,3-adduct) from 2,4,6\_trinitroanisole (TNA) and 'OCH3 is followed by a much slower attack on the l-position, considerable attention has been