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Arene complexes of titanium and zirconium. Synthesis and structure

✍ Scribed by Sergei Troyanov


Book ID
103227398
Publisher
Elsevier Science
Year
1994
Tongue
English
Weight
853 KB
Volume
475
Category
Article
ISSN
0022-328X

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Metallacyclodisiladiazanes of Titanium a
✍ JΓ€ger, Felix ;Roesky, Herbert W. ;Dora, Hendrik ;Shak, Syed ;Noltemeyer, Mathias πŸ“‚ Article πŸ“… 1997 πŸ› Wiley (John Wiley & Sons) 🌐 English βš– 541 KB

A series of metallacyclodisiladiazanes has been prepared. Lithiated (SiMe2NHtBu)z (1) reacts with TiC1, . 2 THF to give (SiMe2NtBu)2TiClz (4). Methylation or fluorination of 4 leads to (SiMe2NtBu)2TiMe, (8) and (SiMezNtBu)zTiFz (9), respectively. The reaction of ZrCL . 2 THF with lithiated 1 or [Si-