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Are Electrocyclization Reactions of (3 Z )-1,3,5-Hexatrienone and Nitrogen Derivatives Pseudopericyclic? A DFT Study

✍ Scribed by Cabaleiro-Lago, Enrique M.; Rodríguez-Otero, Jesús; Varela-Varela, Santiago M.; Peña-Gallego, Angeles; Hermida-Ramón, Jose M.


Book ID
127114346
Publisher
American Chemical Society
Year
2005
Tongue
English
Weight
444 KB
Volume
70
Category
Article
ISSN
0022-3263

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## Abstract 2,4‐Bis‐(4‐methoxyphenyl)‐1,3,2,4‐dithiadiphosphetane‐2,4‐disulfide (Lawesson's reagent) (**1**) reacted with 2‐hydrazino‐3‐methyl‐quinoxaline (**2**) to give [1,2,4,3]‐triazaphospholo[4,5‐__a__]quinoxaline derivative **3**. The Mannich reaction using different amines on compound **3**