Aqueous synthesis of a new 1,3,2-diazaphospholidine
β Scribed by Philip R. Schenkenberg; Charles R. Williams
- Book ID
- 112125110
- Publisher
- Journal of Heterocyclic Chemistry
- Year
- 1977
- Tongue
- English
- Weight
- 139 KB
- Volume
- 14
- Category
- Article
- ISSN
- 0022-152X
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π SIMILAR VOLUMES
2-(AIk-l-enyl)-l,3,2-diazaphospholidine 2-oxides 4, containing the trans-N,N'-dihenzylcyclohexane-l,2diamine chiral auxiliary, may he prepared by palladium(0)-mediated coupling of the phosphorous acid derivative 3 with alkenyi halides. The X-ray crystal structure of the prop-l-enyl compound 4b has b
## Abstract Aromaticβsubstituted derivatives of 1,3,2βdiazaphospholidinβ4βones **2aβg** were readily prepared from 1,3βdiaryl glycinamides **1** by the reaction with hexaethylphosphoric triamide. Their chemical transformation was selectively effected with different thionation reagents to afford thi