✦ LIBER ✦

Aqua(5-nitro-1H-benzimidazole)(oxydiacetato)copper(II)

✍ Scribed by Zhang, Wan-Ju ;Li, Yan-Tuan ;Wu, Zhi-Yong

Publisher: International Union of Crystallography
Year: 2007
Tongue: English
Weight: 661 KB
Volume: 63
Category: Article
ISSN: 1600-5368
DOI: 10.1107/s1600536807055225

No coin nor oath required. For personal study only.

✦ Synopsis

In the molecule of the title compound, [Cu(C 4 H 4 O 5 )-(C 7 H 5 N 3 O 2 )(H 2 O)], the Cu II atom is coordinated by one tridentate oxydiacetate (ODA) dianion, one monodentate nitrobenzimidazole (NBZIM) molecule and one H 2 O molecule, in a distorted square-based pyramidal geometry. In the crystal structure, O-HÁ Á ÁO, N-HÁ Á ÁO and C-HÁ Á ÁO hydrogen bonds link the molecules, forming a three-dimensional network. -Stacking interactions between parallel NBZIM rings consolidate the supramolecular structure [the shortest interplanar distances are 3.360 (3) and 3.269 (3) A ˚]. Related literature For general background, see: Vigato et al. (1990); Bouwman et al. (1990); Ruttimann et al. (1992). For related structures, see: Cao et al. (2004).

📜 SIMILAR VOLUMES

Diaquabis(5-nitro-1H-benzimidazole-κN3

Diaquabis(5-nitro-1H-benzimidazole-κN3)copper(II) dinitrate

✍ Ding, Cai-Feng ;Zhang, Shu-Sheng ;Tian, Bing-Qing ;Li, Xue-Mei ;Xu, Hong ;Ouyang 📂 Article 📅 2005 🏛 International Union of Crystallography 🌐 English ⚖ 214 KB

Poly[[(1H-benzimidazole-κN3)copper(II)

Poly[[(1H-benzimidazole-κN3)copper(II)]-μ3-oxydiacetato]

✍ Cao, Lei ;Li, Ning ;Xu, Duan-Jun 📂 Article 📅 2004 🏛 International Union of Crystallography 🌐 English ⚖ 185 KB

Single-crystal X-ray study T = 295 K Mean '(C±C) = 0.003 A Ê R factor = 0.021 wR factor = 0.052 Data-to-parameter ratio = 15.4 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.

Diaqua(5-nitro-1H-benzimidazole-κN3)(ox

Diaqua(5-nitro-1H-benzimidazole-κN3)(oxydiacetato-κO,O′,O′′)cobalt(II) monohydrate

✍ Zhang, Bing-Yu ;Liu, Jia-Geng ;Xu, Duan-Jun 📂 Article 📅 2005 🏛 International Union of Crystallography 🌐 English ⚖ 376 KB

Diaqua(5-nitro-1H-benzimidazole-jN 3 )(oxydiacetato-jO,O 0 0 0 ,O 0 0 00 0 0 )cobalt(II) monohydrate

Aqua[tris(1H-benzimidazol-2-ylmethyl)

Aqua[tris(1H-benzimidazol-2-ylmethyl)amine]copper(II) bis(perchlorate) 4-nitropyridine N-oxide monohydrate

✍ Wu, Hui-Lu ;Dong, Wen-Kui ;Chen, Ying 📂 Article 📅 2006 🏛 International Union of Crystallography 🌐 English ⚖ 266 KB

In the title structure, [Cu(C~24~H~21~N~7~)(H~2~O)](ClO~4~)~2~·C~5~H~4~N~2~O~3~·H~2~O, the Cu^II^ atom is bonded to a tris(1__H__-benzimidazol-2-ylmethyl)amine (ntb) ligand and a water molecule through four N atoms and one O atom, giving a distorted trigonal–bipyramidal coordination geometry with ap

Chloro{2-[(5-nitrosalicylidene)amino

Chloro{2-[(5-nitrosalicylidene)aminoethyl]-1H-benzimidazole}copper(II)

✍ Qiu, Xiao-Hang ;Wu, Hong-Yan 📂 Article 📅 2004 🏛 International Union of Crystallography 🌐 English ⚖ 173 KB

1-(4-Methylphenylsulfonyl)-5-nitro-1H

1-(4-Methylphenylsulfonyl)-5-nitro-1H-benzimidazole

✍ Rashid, Naghmana ;Hasan, Mashooda ;Tahir, Muhammad K. ;Yusof, Nurdiyana M. ;Yami 📂 Article 📅 2006 🏛 International Union of Crystallography 🌐 English ⚖ 341 KB