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Aqua complexes of 18—crown-6 with H3PO4, H2TiF6, and HNO3: synthesis and vibrational spectra

✍ Scribed by R. Chénevert; A. Rodrigue; D. Chamberland; J. Ouellet; R. Savoie

Publisher
Elsevier Science
Year
1985
Tongue
English
Weight
910 KB
Volume
131
Category
Article
ISSN
0022-2860

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## Abstract New cluster compounds [H~3~O(Ph~3~PO)~3~]~2~[Mo~6~Cl~14~] (I) and [H(Ph~3~PO)~2~]~2~[Re~6~S~6~Br~8~] (II) have been prepared by the reaction of a acetonitrile solution of triphenylphosphane oxide Ph~3~PO with octahedral cluster complexes of molybdenum (H~3~O)~2~Mo~6~Cl~14~·6H~2~O and rh