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Approaches to the Synthesis of Aromatic Diterpenes Oxygenated in the A Ring. Synthesis of Margocin

✍ Scribed by Burnell, Robert H.; Côté, Christian; Théberge, Nathalie

Book ID
121329684
Publisher
American Chemical Society
Year
1993
Tongue
English
Weight
702 KB
Volume
56
Category
Article
ISSN
0163-3864

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A synthetic approach to taxane diterpene
A synthetic approach to taxane diterpenes. A synthesis of the bicyclo[5.3.1]undecenone ring system
✍ Yasuo Ohtsuka; Takeshi Oishi 📂 Article 📅 1986 🏛 Elsevier Science 🌐 French ⚖ 253 KB

Bicyclo[5.3.l]undecenone 2 corresponding to A and B rings in taxane diterpenes was synthesized. The eight-membered ring was constructed by a baseinduced intramolecular cyclization of twelve-membered lactam sulfoxides 15. 204 lja,b ya,bl,b2 isomer NC-S J K \*H,6 5 4 9 07 / 11' 1 3 10 -. 2 0 H R NHMe