Approaches to avermectin assembly: elaboration of an α-L-oleandrosyl-α-L-oleandroside derivative
✍ Scribed by Anthony G.M. Barrett; Todd A. Miller
- Publisher
- Elsevier Science
- Year
- 1988
- Tongue
- French
- Weight
- 131 KB
- Volume
- 29
- Category
- Article
- ISSN
- 0040-4039
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📜 SIMILAR VOLUMES
The reagent chloro-B-cyanoethyl-N,N-diisopropylamino-phosphoramidite reacts smoothly with the anomeric hydroxyl group of a properly protected (benzyl) a-L-fucopyranose to afford a relatively stable phosphite intermediate in high yield. The latter can easily be converted into valuable a-L-fucopyranos
## Abstract The monomer __N__′‐octadecyl‐__N__^α^‐(4‐vinyl)‐benzoyl‐L‐phenylalanineamide (**4**) based on L‐phenylalanine has been simply but effectively synthesized, and its self‐assembling properties have been investigated. FTIR and a variable‐temperature ^1^H NMR spectroscopic investigation demo