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Approach to the Blues: A Highly Flexible Route to the Azulenes.

โœ Scribed by Sebastien Carret; Aurelien Blanc; Yoann Coquerel; Mikael Berthod; Andrew E. Greene; Jean-Pierre Depres


Publisher
John Wiley and Sons
Year
2005
Weight
21 KB
Volume
36
Category
Article
ISSN
0931-7597

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## Dedicated to Dr. Jean-Louis Luche on the occasion of his retirement Nearly a century and a half ago, Septimus Piesse applied the descriptive name azulene to azure-blue distillates from various sources, such as chamomile, yarrow, and wormwood. However, it was only in 1937 that Placidus Plattner

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4 ) (14.9g, 50mmol) is refluxed with dimethyl acetylenedicarboxylate (7.8 g, 55 mmol) in anhydrous benzene (100 ml) for 4 h. After removal of the benzene the residue [ ( S ) / ( 6) ] is dissolved in acetone (1.7 liter) and irradiated in a Pyrex vessel ( O T ) with the light from a Hanau T Q 2024 2OO

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