## Abstract The potential advantages of ^13^C‐(^1^H‐noise decoupled) spectroscopy (in the __Fourier__ transform mode) over ^1^H‐spectroscopy for the quantitative investigation of molecular dynamic process is discussed. The __Cope__ rearrangement in bullvalene, an example of complex exchange of spin
✦ LIBER ✦
Applications of carbon-13 resonance spectroscopy—XV : The degenerate cope-rearrangement of bullvalene
✍ Scribed by H. Günther; J. Ulmen
- Book ID
- 108372503
- Publisher
- Elsevier Science
- Year
- 1974
- Tongue
- French
- Weight
- 470 KB
- Volume
- 30
- Category
- Article
- ISSN
- 0040-4020
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Homotropylidene and its bridge derivatives (e.g.bullvalene(l)) make a Cope rearrangement in a thermal process."s Recently much attention has been focused on these compounds from dynamic NMR spectroscopy 4,5 as well as synthetic and photochemical standpoints. 627 Moreover, in a theoretical field, th
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