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Application of the oxa-di-π-methane photoisomerization in the rearrangement of carbocycles possessing bridgehead unsaturation

✍ Scribed by R. Michael Corbett; Chee-Seng Lee; Michelle M. Sulikowski; Joseph Reibenspies; Gary A. Sulikowski

Publisher
Elsevier Science
Year
1997
Tongue
French
Weight
596 KB
Volume
53
Category
Article
ISSN
0040-4020

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✦ Synopsis

Studies directed toward an application of the oxa-di-pi-methane (ODPM) photoisomerization to convert a bicyclol4.4.1]undecene (1) to a bicyclo15.3.1]undecene (3) are described, This transformation, which is equivalent to a 1,2-acyl shift, could find utility in the synthesis of bioactive natural products possessing bridgehead unsaturation.

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