The hypernerted chsin approximation is used fo calculate t&e den&y and charge profiles ar.d rhe potential difference of a fluid of &aged hard spheres nex a charred planar wdl. The charge profile is not monotonic. Recently, we [I 21 have shown that the hypernetted chain (HNC) approximation integral e
Application of the generalized mean spherical approximation to the electric double layer
β Scribed by Douglas Henderson; Lesser Blum
- Publisher
- Elsevier Science
- Year
- 1980
- Weight
- 133 KB
- Volume
- 101
- Category
- Article
- ISSN
- 0167-2584
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π SIMILAR VOLUMES
The electnc double laler capa~~tance for a hard sphere lon-chpolc system m the nelghbourhood of a plane charged ## wall IS calculated m the mean field approxlmatton To order Ka the capacitance predicts the same structural features as the hISA capacitance Carme and Chan [l] have solved the mean s
Activity coefficients and thermodynamic association constants have been estimated for NaBr, NaCI, Nal, NaCIOJ, Bu,NBr, BuJNI, and BuJNC103 electrolytes in methanol by means of a tit of experimental data to theory using the unrestricted version of the mean spherical approximation. Realistic sizes for