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Application of the EPR spin-trapping technique for the investigation of the reactions of carbonate, bicarbonate, and phosphate anions with hydroxyl radicals generated by the photolysis of H2O2

โœ Scribed by Jan Kochany; Ewa Lipczynska-Kochany


Book ID
116078918
Publisher
Elsevier Science
Year
1992
Tongue
English
Weight
603 KB
Volume
25
Category
Article
ISSN
0045-6535

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โœ R. Lesclaux; F. Caralp ๐Ÿ“‚ Article ๐Ÿ“… 1984 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 560 KB

The rate constants for reactions (4) and (5) ( 4 ) CFCI,O, 7 NO -+CFCI,O + NO, ( 5 ) CFCI,O, + NO, + M -CFCI,O,NO, -M were determined at room temperature by pulsed laser photolysis and time resolved mass spectrometry. A description of the experimental setup is given. CFCI,O, radicals were generated