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Application of Sharpless Asymmetric Dihydroxylation of Thienyl- and Benzothienyl Acrylates and Crotonates.

โœ Scribed by Carlo Bonini; Lucia Chiummiento; Margherita De Bonis; Maria Funicello; Paolo Lupattelli; Rocco Pandolfo


Publisher
John Wiley and Sons
Year
2007
Weight
26 KB
Volume
38
Category
Article
ISSN
0931-7597

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An Efficient Synthesis of (-)-Pestalotin and Its Enantiomer Using Sharpless Asymmetric Dihydroxylation. -The title compound (IV), a gibberellin synergist isolated from a phytopathogenic fungus Pestaltia cryptomeriaecola, is prepared using Sharpless asymmetric dihydroxylation as the key step. A simi