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Application of Phosphine−Oxazoline Ligands in Ir-Catalyzed Asymmetric Hydrogenation of Acyclic Aromatic N -Arylimines

✍ Scribed by Trifonova, Anna; Diesen, Jarle S.; Chapman, Christopher J.; Andersson, Pher G.


Book ID
127360186
Publisher
American Chemical Society
Year
2004
Tongue
English
Weight
55 KB
Volume
6
Category
Article
ISSN
1523-7060

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Asymmetric hydrogenation of aromatic ole
✍ Guopin Xu; Scott R. Gilbertson 📂 Article 📅 2003 🏛 Elsevier Science 🌐 French ⚖ 196 KB

The synthesis of a series of phosphine-oxazoline ligands is reported. This ligands are synthesized by reaction of a phosphine chloride with the secondary nitrogen of proline. Upon coordination to iridium the resulting complexes can be used in the asymmetric hydrogenation of simple olefins. The effec