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Application of (2R,3R)-dihydroxy-1,2,3,4-tetrahydronaphthalene to asymmetric synthesis

✍ Scribed by Fulvia Orsini; Sabina Rinaldi

Publisher: Elsevier Science
Year: 1997
Tongue: English
Weight: 712 KB
Volume: 8
Category: Article
ISSN: 0957-4166
DOI: 10.1016/s0957-4166(97)00088-8

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✦ Synopsis

2R,3R)-Dihydroxy-tetrahydronaphthalene, prepared via an efficient chemoenzymatic procedure from naphthalene, has been successfully tested, as a chiral auxiliary in diastereoselective conjugate additions of lithium dialkylcuprates to 0t,13-unsaturated esters and in stereoselective alkylations of 13-ketoesters. (~

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