Application of 2D Nmr Spectroscopy to the Structural Establishment of the Major Hydrolysis Product of Aescin
β Scribed by Agrawal, Pawan K.; Thakur, Raghunath S.; Shoolery, James N.
- Book ID
- 120586003
- Publisher
- American Chemical Society
- Year
- 1991
- Tongue
- English
- Weight
- 206 KB
- Volume
- 54
- Category
- Article
- ISSN
- 0163-3864
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π SIMILAR VOLUMES
Using 1D and 2D NMR spectra, the compounds obtained, in a mixture, in the reaction of glycerol with iodine were identified as the two isomers (cis and trans) of 2-iodomethyl-5-hydroxymethyl-1,4-dioxane and the two isomers (cis and trans) of 2-iodomethyl-6-hydroxymethyl-1,4-dioxane. Thus, the composi
COSY and NOESY spectra (400 MHz) have been used to complete the assignment of the 'H NMR spectra of 1and 3-nitrobenzo[e]pyrene. Both compounds show strong bay region nuclear Overhauser enhancement and significant coupling across bay regions. Both compounds also exhibit extensive long-range couplings